Spin-orbit interaction induces charge beatings in a lightwave-STM – single molecule junction

Recent lightwave-STM experiments have shown space and time resolution of single molecule vibrations directly on their intrinsic length timescales. We address here theoretically the electronic dynamics a copper-phthalocyanine in explored within pump-probe cycle scheme. The spin-orbit interaction metallic center induces beatings electric charge flowing through as function delay between pump probe pulses. Interference quasidegenerate anionic states intertwined associated spin pseudospin degrees freedom are key aspects such phenomenon. study domain generalized master-equation approach.